VB.NET
dgv1.Columns("col1").DefaultCellStyle.Alignment = _
DataGridViewContentAlignment.MiddleCenter
dgv1.Columns("col1").HeaderCell.Style.Alignment = _
DataGridViewContentAlignment.MiddleCenter
C#
dgv1.Columns["col1"].DefaultCellStyle.Alignment =
DataGridViewContentAlignment.MiddleCenter;
dgv1.Columns["col1"].HeaderCell.Style.Alignment =
DataGridViewContentAlignment.MiddleCenter;